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Site-selective carbon-carbon bond formation in unprotected monosaccharides using photoredox catalysis.

Ieng Chim Steven Wan, Martin D Witte, Adriaan J Minnaard
Chemical Communications : Chem Comm 2017 May 3
Site-selective photoredox reactions with somophiles readily enable branching of the carbon skeleton of unprotected glucosides, allosides, and xylosides regioselectively at C3. These reactions open the possibility of selective C-C bond formation in monosaccharides without multi-step protection-deprotection strategies.

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