We have located links that may give you full text access.
Large-Scale Synthesis of Monodisperse UiO-66 Crystals with Tunable Sizes and Missing Linker Defects via Acid/Base Co-Modulation.
ACS Applied Materials & Interfaces 2017 May 4
Beyond their pore structures and surface chemistry, precise controls over other attributes of metal-organic frameworks (MOFs) such as shapes, sizes, and defects are also favorable to their fundamental studies and applications but still remain challenging. Herein, we reported an acid/base co-modulation strategy to the large-scale synthesis of monodisperse UiO-66 crystals with acetic acid for modulating crystal shape and with triethylamine (TEA) as a base for controlling the nucleation of crystallization and tuning the formation of missing linker defects via promoting presumably the singe deprotonation of terephthalic acid linkers. The obtained monodisperse MOF crystals have a well-defined octahedral shape, tunable sizes ranging from ∼500 nm to ∼2 μm, and high thermal stability. Their assembled-monolayers are responsive to methanol vapor with the crystal size-dependent and defect-relevant sensing performances.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app