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Dehydrogenative cross-coupling of o-carborane with thiophenes via Ir-catalyzed regioselective cage B-H and C(sp 2 )-H activation.
Chemical Communications : Chem Comm 2017 April 28
Ir-Catalyzed -COOH directed site-selective B-H/C-H dehydrogenative cross-coupling of o-carborane with thiophenes has been achieved for the first time. Without any pre-functionalization, carboranyl carboxylic acids and thiophenes can serve as suitable coupling partners, resulting in the preparation of 4-thienyl-o-carboranes in a simple one-pot process for potential applications in materials.
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