Efficient Criterion To Evaluate Linear Response Theory in Optical Transitions.

The role of the Gaussian statistics on the solvation dynamics upon the photon excitation of the chromophore is deeply explored. The linear response theory for the fluorescence Stokes shift is investigated. An analytical formulism is presented to recast Stokes shift into the contributions of the equilibrium time correlation functions of the solute-solvent interactions on the excited-state surface, and the latter is further reformed and depicted by the time relaxation of the moment. As the first application of the formulism in the molecular dynamics simulations, it is verified that the efficiency of the linear response theory relies on the Gaussian characteristics of the dominant moments in terms of the Stokes shift, which is identified by the same relaxation dynamics between those moments and the linear order one. The comparisons between the above observations on the linearity of Stokes shift and the explanations in the literature are discussed. The key finding is the development of explicit criterion to measure the appropriateness of applying linear response theory.