Add like
Add dislike
Add to saved papers

Investigation of the Halogenate-Hydrogen Peroxide Reactions Using the Electron Paramagnetic Resonance Spin Trapping Technique.

The differences in the mechanism of the halogenate reactions with the same oxidizing/reducing agent, such as H2 O2 contribute to the better understanding of versatile halogen chemistry. The reaction between iodate, bromate, and chlorate with hydrogen peroxide in acidic medium at 60 °C is investigated by using the electron paramagnetic resonance (EPR) spin trapping technique. Essential differences in the chemistry of iodate, bromate, and chlorate in their reactions with hydrogen peroxide have been evidenced by finding different radicals as governing intermediates. The reaction between KIO3 and H2 O2 is supposed to be the source of IO2 • radicals. The KBrO3 and H2 O2 reaction did not produce any EPR signal, whereas the KClO3 -H2 O2 system was found to be a source of HO• radical. Moreover, KClO3 dissolved in sulfuric acid without hydrogen peroxide produced HO• radical as well. The minimal-core models explaining the origin of obtained EPR signals are proposed. Current findings suggested the inclusion of IO2 • and HOO• radicals, and ClO2 • and HO• radicals in the particular kinetic models of iodate-hydrogen peroxide and chlorate-hydrogen peroxide systems, as well as possible exclusion of BrO2 • radical from the kinetic scheme of the bromate-hydrogen peroxide system. Obtained results may pave the way for understanding more complex, nonlinear reactions of these halogen-containing species.

Full text links

We have located links that may give you full text access.
Can't access the paper?
Try logging in through your university/institutional subscription. For a smoother one-click institutional access experience, please use our mobile app.

For the best experience, use the Read mobile app

Mobile app image

Get seemless 1-tap access through your institution/university

For the best experience, use the Read mobile app

All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.

By using this service, you agree to our terms of use and privacy policy.

Your Privacy Choices Toggle icon

You can now claim free CME credits for this literature searchClaim now

Get seemless 1-tap access through your institution/university

For the best experience, use the Read mobile app