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Cobalt-catalysed Markovnikov selective hydroboration of vinylarenes.

Jingying Peng, Jamie H Docherty, Andrew P Dominey, Stephen P Thomas
Chemical Communications : Chem Comm 2017 April 26
A bipyridiyl-oxazoline cobalt catalyst t Bu BPOCoCl2 has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and NaOt Bu as the in situ activator with up to >98 : 2 branched : linear selectivity (24 examples, 45-92% isolated yield).

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