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1,2-Benzothiazines from Sulfoximines and Allyl Methyl Carbonate by Rhodium-Catalyzed Cross-Coupling and Oxidative Cyclization.

Jian Wen, Deo Prakash Tiwari, Carsten Bolm
Organic Letters 2017 April 8
4-Unsubstituted 1,2-benzothiazines are prepared from sulfoximines and allyl methyl carbonate by Rh(III)-catalyzed domino allylation/oxidative cyclization. A wide range of functional groups on the sulfoximine are tolerated. A plausible mechanism is proposed, and chemical modifications of the products have been explored.

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