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Ligand controlled switchable selectivity in ruthenium catalyzed aerobic oxidation of primary amines.
Chemical Communications : Chem Comm 2017 April 5
A ligand controlled catalytic system for the aerobic oxidation of 1° amines to nitriles and imines has been developed where the varying π-acidic feature of BIAN versus phen in the frameworks of ruthenium catalysts facilitates switchable selectivity.
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