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Extraction of minor actinides, lanthanides and other fission products by silica-immobilized BTBP/BTPhen ligands.
Chemical Communications : Chem Comm 2017 April 5
Novel BTBP [bis-(1,2,4-triazin-3-yl)-2,2'-bipyridine]/BTPhen [bis-(1,2,4-triazin-3-yl)-1,10-phenanthroline] functionalized silica gels have been developed to extract minor actinides, lanthanides and other fission products. BTPhen functionalized silica gel is capable of near-quantitative removal of Am(iii) in the presence of Eu(iii) from aqueous HNO3 , while BTBP functionalized silica gel is able to remove problematic corrosion and fission products that are found in PUREX raffinates.
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