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UV-light promoted C-H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex.
Chemical Communications : Chem Comm 2017 March 29
Iridium(i) carbonyl complex [Ir(2,6-(Pt Bu2 CH2 )2 C6 H3 )(CO)] undergoes reversible C-H bond activation of benzene and a series of fluorobenzenes on UV irradiation. Exclusive ortho-selectivity is observed in reactions of fluorobenzene and 1,2-difluorobenzene.
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