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Phenacyl azides as efficient intermediates: one-pot synthesis of pyrrolidines and imidazoles.
Organic & Biomolecular Chemistry 2017 March 29
Phenacyl azides were decomposed in basic media to generate N-unsubstituted imines which were reacted with cyclic amino acids to give an azomethine ylide that underwent [3 + 2] cycloaddition with maleimides and N-unsubstituted imines to yield various diastereoselective pyrrolidines and imidazoles respectively in a one-pot three component manner with good to excellent yields.
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