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A luminescent polyoxoniobate lanthanide derivative {Eu 3 (H 2 O) 9 [Nb 48 O 138 (H 2 O) 6 ]} 27- .
Chemical Communications : Chem Comm 2017 March 29
A europium-containing isopolyoxoniobate with the formula (CN3 H6 )7 K3 H17 {Eu3 (H2 O)9 Nb48 O138 (H2 O)6 }·40H2 O is synthesized under the protection of citric acid. ESI-MS spectra show that the polyoxoanion structural unit {Eu3 (H2 O)9 [Nb48 O138 (H2 O)6 ]}27- is intact in aqueous solution. Moreover, its solid-state luminescence displays a red emission with the long lifetime of 258 μs.
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