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Re-Determination of the Crystal Structure of MIL-91(Al).

Nele Hermer, Michael T Wharmby, Norbert Stock
Zeitschrift Für Anorganische und Allgemeine Chemie 2017 January
The structure of one of the first permanently porous metal phosphonates, MIL-91(Al) was re-determined using high resolution synchrotron powder X-ray diffraction data. The new model is in a lower symmetry space group, with no disordered ligands in the structure, whilst remaining otherwise consistent with the reported compound. New milder synthetic conditions were also developed.

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