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N 1 -Selective alkenylation of 1-sulfonyl-1,2,3-triazoles with alkynes via gold catalysis.
Organic & Biomolecular Chemistry 2017 March 29
A N1 -selective alkenylation of 1-sulfonyl-1,2,3-triazoles with alkynes via gold catalysis is reported. N1 -Vinyl substituted 1,2,3-triazoles were selectively prepared in up to 92% yield through the sulfonyl group of 1,2,3-triazole derivatives transformed to alkenyl groups in a "one-pot two steps" manner. This method provided a new method for the synthesis of potentially biological-active vinyl-triazole building blocks.
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