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Ring-opening of cyclic ethers by aluminum hydridotriphenylborate.

Molecular aluminum hydride [(L)AlH2 ] (L = Me3 TACD) reacted with 2 equiv. of BPh3 in THF or THP to give the cationic alkoxides [(L)Al(OR)][HBPh3 ] (R = nBu, nPent) by facile ring-opening of the cyclic ethers. The Cα -O bond cleavage which involves the isolable intermediate [(L)AlH][HBPh3 ] is a result of hydride transfer to Cα from [HBPh3 ]- .

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