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Journal Article
Research Support, Non-U.S. Gov't
Bis-15-crown-5-ether-pillar[5]arene K + -Responsive Channels.
Organic Letters 2017 March 18
An artificial selective K+ channel is formed from the supramolecular organization on bis(benzo-15-crown-5- ether-ureido)-pillar[5]arene compound. This channel achieves a selectivity of SK+ /Na+ = 5 for an initial transport rate of kK+ = 3.2 × 10-3 s-1 . The cation-file diffusion occurs via selective macrocyclic-filters anchored on inactive supporting pillar[5]arene relays. The sandwich-type binding geometry of the K+ cation by two 15-crown-5 moieties sites is a key feature influencing channel efficiency.
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