Layered A 2 Sn 3 S 7 ·1.25H 2 O (A = Organic Cation) as Efficient Ion-Exchanger for Rare Earth Element Recovery.

Exploring new ion-exchangers for the recovery of rare earth elements (REEs) and recycling is worthwhile for the high-tech industry and an eco-friendly sustainable economy. The efficient enrichment of low concentration REE from complex aqueous solutions containing large excess of competitive ions is challenging. Here we present a chalcogenide example as a superior REE ion-exchanger efficiently removing them from very complex aqueous solutions, (Me2 NH2 )1.33 (Me3 NH)0.67 Sn3 S7 ·1.25H2 O (FJSM-SnS). The material exhibits fast and efficient ion exchange behavior with short equilibrium time (<5 min), high adsorption capacity (139 mg/g for Eu, 147 mg/g for Tb, 126 mg/g for Nd), wide pH resistance (1.9-8.5), the largest distribution coefficient (Kd ) value of 6.5 × 106 mL/g, good selectivity against Al3+ , Fe3+ , and Na+ ions, and high recovery rate (>99%) at low concentrations. Moreover, after ion-exchange, the REE in corresponding exchanged products could be easily recovered by elution. FJSM-SnS has superior capacity and faster absorption kinetics than other states of the artificial REE sorbents such as Al2 O3 /EG, clay minerals, zeolite, and activated carbon.