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Self-repairing metal-organic hybrid complexes for reinforcing immobilized chloroperoxidase reusability.

A self-repairing metal-enzyme hybrid nanocatalyst with a sodium alginate (SA) coating was reported in this study. Compared with free CPO, immobilized chloroperoxidase (CPO) has similar Km and Kcat values. SA-coated CPO@Ca3 (PO4 )2 hybrid composites displayed robust reusability under acidic conditions, maintaining more than 85% of the catalytic activity after 12 recycles.

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