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Electrochemical [ 11 C]CO 2 to [ 11 C]CO conversion for PET imaging.
Chemical Communications : Chem Comm 2017 March 8
The development of a novel electrochemical methodology to generate carbon-11 carbon monoxide ([11 C]CO) from cyclotron-produced carbon-11 carbon dioxide ([11 C]CO2 ) using Ni(cyclam) and Zn(cyclen) complexes is described. This methodology allows up to 10% yields of [11 C]CO from [11 C]CO2 . Produced [11 C]CO was subsequently converted to [11 C]N-benzylbenzamide under mild conditions with a radiochemical purity (RCP) of >98%.
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