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Journal Article
Research Support, Non-U.S. Gov't
Inhibition and Stabilization: Cucurbituril Induced Distinct Effects on the Schiff Base Reaction.
Journal of Organic Chemistry 2017 March 18
The different effects of cucurbit[7]uril (CB[7]) on the Schiff base reactions in aqueous solution were explored by 1 H NMR spectroscopy and single X-ray crystallography. With CB[7], the condensation reaction of aldehyde and primary amine is dramatically inhibited. In contrast, the presence of CB[7] does tremendously stabilize iminium cation in water through ion-dipole interactions. A single crystal structure of the complex of iminium ion 7 with CB[7] grown in water is reported.
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