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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
Oxidation of β-Ketoamides: The Synthesis of Vicinal Tricarbonyl Amides.
Journal of Organic Chemistry 2017 April 8
A facile and direct oxidative reaction for the synthesis of vicinal tricarbonyl amides in moderate to excellent yields (53-88%) was developed starting from readily available β-ketoamides in the presence of phenyliodine(III) bis(trifluoroacetate). The resulting products possess significant synthetic potential, making this approach a valuable addition to the group of traditional methods already available for the preparation of these molecules.
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