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Exploring the Detection of Metal Ions by Tailoring the Coordination Mode of V-Shaped Thienylpyridyl Ligand in Three MOFs.

Li-Juan Han, Wei Yan, Shu-Guang Chen, Zhen-Zhen Shi, He-Gen Zheng
Inorganic Chemistry 2017 March 7
By employing a rational design approach, we synthesized three luminescent metal-organic frameworks (MOFs) 1-3 affording different coordination modes of V-shaped thienylpyridyl ligand. Their application in detecting metal ions was explored, and the mechanism was inferred. And the result exhibits that MOF 3 is a dual-responsive luminescent probe for Fe3+ and Al3+ ions.

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