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Non-sensitized selective photochemical reduction of CO 2 to CO under visible light with an iron molecular catalyst.
Chemical Communications : Chem Comm 2017 March 3
A substituted tetraphenyl iron porphyrin, bearing positively charged trimethylammonio groups at the para position of each phenyl ring, demonstrates its ability as a homogeneous molecular catalyst to selectively reduce CO2 to CO under visible light irradiation in organic media without the assistance of a sensitizer and no competitive hydrogen evolution for several days.
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