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Highly efficient cold-white light emission in a [Au 2 CuCl 2 (P∩N) 2 ]PF 6 type salt.
In the trinuclear, heterometallic cluster compound [Au2 CuCl2 (P∩N)2 ]PF6 metallophilic interactions give rise to very efficient cold-white light emission as a result of at least two thermally non-equilibrated emissive triplet states (one of mainly Cu → py and the other of Au → py character, respectively) with exceptional spin-orbit coupling and short emission lifetimes, which are competitive to PtII - and IrIII -based emitters.
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