Thermodynamics and Photodynamics of a Monoprotonated Porphyrin Directly Stabilized by Hydrogen Bonding with Polar Protic Solvents.

Addition of 1 equiv of TFA to an acetone solution containing dodecaphenylporphyrin (H2 DPP) in the presence of 10 % MeOH (v/v) resulted in selective formation of a monoprotonated form (H3 DPP+ ), in sharp contrast to protonation of H2 DPP directly affording a diprotonated form (H4 DPP2+ ) in acetone in the absence of MeOH. The crucial role of MeOH for selective H3 DPP+ formation was interpreted as hydrogen-bonding stabilization of H3 DPP+ , since a MeOH molecule was found to form hydrogen bonds with an NH proton of H3 DPP+ in the crystal. The selectivity of H3 DPP+ formation was evaluated by the formation yield of H3 DPP+ , which increased when elevating the portion of MeOH (0-10 %) in acetone with saturation behavior, suggesting that H3 DPP+ is stabilized by hydrogen bonding with MeOH even in solution, together with the thermodynamic parameters determined from a van't Hoff plot based on the spectroscopic titration. Femto- and nanosecond laser flash photolysis allowed us to elucidate the photodynamics of H3 DPP+ in intermolecular photoinduced electron transfer (ET) from ferrocene derivatives as one-electron donors to the triplet excited state of H3 DPP+ as an electron acceptor. The second-order rate constants of the ET reactions were evaluated in light of the Marcus theory of ET. The reorganization energy of ET was determined to be 1.87 eV, which is slightly larger than that of H4 DPP2+ in acetonitrile (1.69 eV), due to larger structural change upon ET than that of H4 DPP2+ .