We have located links that may give you full text access.
Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 2 .
Dalton Transactions : An International Journal of Inorganic Chemistry 2017 Februrary 22
Three novel zero-dimensional quaternary chalcohalides, Ba4 Ge3 S9 Cl2 , Ba4 Si3 Se9 Cl2 and Ba4 Ge3 Se9 Cl2 , which crystallize in the polar noncentrosymmetric space group P63 (no. 173), have been rationally synthesized by a tailored approach on the basis of unique [M3 Q9 ]6- (M = Ge, Q = S; M = Ge/Si, Q = Se) units with Ba2+ cations and Cl- anions occupying the interspaces. The [M3 Q9 ]6- units which consist of three Q-corner-sharing [MQ4 ]4- tetrahedra, are arranged along the 63 screw axis. Remarkably, Ba4 Ge3 S9 Cl2 exhibits a strong powder second harmonic generation (SHG) response that is 2.4 times that of benchmark AgGaS2 at a laser radiation of 2.05 μm in the same particle size range of 46-74 μm. Furthermore, theoretical studies based on the density functional theory helped to gain insight into the origin of the SHG.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app