We have located links that may give you full text access.
Cleavage of Dinitrogen from Forming Gas by a Titanium Molecular System under Ambient Conditions.
Chemistry : a European Journal 2017 March 14
Simple exposure of a hexane solution of [TiCp*Me3 ] (Cp*=η5 -C5 Me5 ) to an atmosphere of commercially available and inexpensive forming gas (H2 /N2 mixture, 13.5-16.5 % of H2 ) at room temperature leads to the methylidene-methylidyne-nitrido cube-type complex [(TiCp*)4 (μ3 -CH)(μ3 -CH2 )(μ3 -N)2 ] via dinitrogen cleavage. This paramagnetic compound reacts with [D1 ]chloroform to give the titanium(IV) methylidyne-nitrido species [(TiCp*)4 (μ3 -CH)2 (μ3 -N)2 ], whereas its one-electron oxidation with AgOTf or [Fe(η5 -C5 H5 )2 ](OTf) (OTf=O3 SCF3 ) yields the diamagnetic ionic derivative [(TiCp*)4 (μ3 -CH)(μ3 -CH2 )(μ3 -N)2 ](OTf). The μ3 -nitrido ligands of the methylidyne-nitrido cubane complex can be protonated with [LutH](OTf) (Lut=2,6-lutidine) or hydrogenated with NH3 ⋅BH3 to afford μ3 -NH imido moieties.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app