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An important role of temperature dependent scattering time in understanding the high temperature thermoelectric behavior of strongly correlated system: La 0.75 Ba 0.25 CoO 3 .

In the present work, we report the temperature dependent thermopower (α) behavior of La0.75 Ba0.25 CoO3 compound in the temperature range 300-600 K. Using the Heikes formula, the estimated value of α corresponding to high-spin configuration of Co3+ and Co4+ ions is found to be  ∼16 [Formula: see text], which is close to the experimental value, ∼13 [Formula: see text], observed at  ∼600 K. The temperature dependent TE behavior of the compound is studied by combining the WIEN2K and BoltzTrap code. The self consistency field calculations show that the compound have ferromagnetic ground state structure. The electronic structure calculations give half metallic characteristic with a small gap of  ∼50 meV for down spin channel. The large and positive value for down spin channel is obtained due to the unique band structure shown by this spin channel. The temperature dependent relaxation time for both the spin-channel charge carriers is considered to study the thermopower data in temperature range 300-600 K. For evaluation of α, almost linear values of [Formula: see text] and a non-linear values of [Formula: see text] are taken into account. By taking the temperature dependent values of relaxation time for both the spin channels, the calculated values of α using two current model are found to be in good agreement with experimental values in the temperature range 300-600 K. At 300 K, the calculated value of electrical conductivity by using the same value of relaxation time, i.e. 0.1 [Formula: see text] 10-14 seconds for spin-up and [Formula: see text] seconds for spin-dn channel, is found to be equal to the experimentally reported value.

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