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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
Palladium-Catalyzed Redox-Neutral N-O/C(sp 3 )-H Functionalization of Aryl Oximes with Isocyanides.
Organic Letters 2017 Februrary 4
A redox-neutral palladium-catalyzed N-O/C(sp3 )-H functionalization of aryl oximes with isocyanides has been developed. Various pyrrole derivatives were prepared in good to excellent yields through oxime carbamate as a key intermediate and internal oxidant in this process. Furthermore, this transformation also features readily available starting materials, good functional group tolerance, and excellent regioselectivity.
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