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Controllable Remote C-H Bond Functionalization by Visible-Light Photocatalysis.

Angewandte Chemie 2017 January 21
Remote control: New strategies for the activation of remote C(sp(3) )-H bonds by photoredox-catalyzed (PC) radical translocation via O- and N-centered radicals have recently been described. These methods enable the controlled and site-selective functionalization of inert C(sp(3) )-H bonds and provide new opportunities for reaction design (HAT=hydrogen atom transfer).

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