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A Cryptand Metal-Organic Framework as a Platform for the Selective Uptake and Detection of Group I Metal Cations.

Sergey A Sapchenko, Pavel A Demakov, Denis G Samsonenko, Danil N Dybtsev, Martin Schröder, Vladimir P Fedin
Chemistry : a European Journal 2017 Februrary 17
The metal-organic framework (MOF) complex (H3 O)2 [Zn4 (ur)(Hfdc)2 (fdc)4 ] (1, ur=urotropine, H2 fdc=furan-2,5-dicarboxylic acid) incorporates cryptand-like cavities, which can be used to separate and detect Rb+ and Cs+ optically. This is the first example of the effective employment of a MOF material for optical detection of these cations.

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