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Three-component carboarylation of unactivated imines with arynes and carbon nucleophiles.
Chemical Communications : Chem Comm 2017 Februrary 5
With 2-(trimethylsilyl)aryl triflates as aryne precursors, an unprecedented three-component carboarylation reaction of unactivated imines with arynes and carbon nucleophiles has been developed to access a variety of functionalized tertiary amines under transition metal-free conditions. Suitable carbon nucleophiles include chloroform, acetonitrile, and methyl propiolate.
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