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Morphology transition in helical tubules of a supramolecular gel driven by metal ions.
Chemical Communications : Chem Comm 2017 January 27
Our aim to access a particular chemical functionality on helical tubules has been achieved by the rational molecular design and synthesis of glucono-appended cardanol derivatives. For the first time, we report a chiral molecular packing with α-helical tubules, and chiral symmetry-breaking upon exposure to Cu2+ that generated the final ordered structure via an in situ morphological transition without undergoing any phase change.
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