We have located links that may give you full text access.
The Cobalt cyclo-P4 Sandwich Complex and Its Role in the Formation of Polyphosphorus Compounds.
Angewandte Chemie 2017 Februrary 2
A synthetic approach to the sandwich complex [Cp'''Co(η(4) -P4 )] (2) containing a cyclo-P4 ligand as an end-deck was developed. Complex 2 is the missing homologue in the series of first-row cyclo-Pn sandwich complexes, and shows a unique tendency to dimerize in solution to form two isomeric P8 complexes [(Cp'''Co)2 (μ,η(4) :η(2) :η(1) -P8 )] (3 and 4). Reactivity studies indicate that 2 and 3 react with further [Cp'''Co] fragments to give [(Cp'''Co)2 (μ,η(2) :η(2) -P2 )2 ] (5) and [(Cp'''Co)3 P8 ] (6), respectively. Furthermore, complexes 2, 3, and 4 thermally decompose forming 5, 6, and the P12 complex [(Cp'''Co)3 P12 ] (7). DFT calculations on the P4 activation process suggest a η(3) -P4 Co complex as the key intermediate in the synthesis of 2 as well as in the formation of larger polyphosphorus complexes via a unique oligomerization pathway.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app