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Symmetry breaking above room temperature in an Fe(ii) spin crossover complex with an N 4 O 2 donor set.
Chemical Communications : Chem Comm 2017 January 25
[Fe(qsal-Cl)2 ] is one of the few known Fe(ii) spin crossover compounds with an N4 O2 donor atom environment. It shows an abrupt two-step spin transition at 308 and 316 K and importantly, symmetry breaking at the highest temperature reported, to date, in spin crossover compounds.
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