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Unique optical properties of Eu 3+ doped l-histidine hydrochloride mono hydrate single crystals from low temperature growth technique.

A low-temperature solution method was utilized to grow single crystals of Eu3+ doped l-histidine hydrochloride monohydrate. The quality of the crystals was confirmed by high-resolution X-ray diffraction measurements with full width at half maximum (FWHM) of rocking curve at 8arc per sec. The incorporation of Eu3+ ions into the lattice was confirmed by functional group analysis using Fourier Transform Infrared (FTIR) spectroscopy. The amount of Eu3+ ions was found to be 0.08 weight (%) using energy dispersive X-ray analysis. The crystal's thermal and mechanical properties were tested as well. The unique spectral properties such as UV-Vis transmittance, nonlinear optical efficiency (NLO), photoluminescence (PL) and its lifetime were measured. The PL study revealed that the intensity of 5 D0 →7 F2 emission of Eu3+ is stronger than that of 5 D0 →7 F1 emission and the decay measurement showed a life time of 7.2410μs. The photoluminescence results prove that l-histidine hydrochloride monohydrate is a new, highly efficient host material for europium ion red emissions.

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