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Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD.
Chemistry : a European Journal 2017 March 3
Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.
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