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Coupling of C(sp 3 )-H bonds with C(sp 2 )-O electrophiles: mild, general and selective.
Chemical Communications : Chem Comm 2017 January 18
Herein is reported the mild and general coupling of amine/ether C(sp3 )-H bonds with various kinds of C(sp2 )-O electrophiles with high selectivity and efficiency. Valuable allylic/benzylic amines are generated in moderate to excellent yields. The utility of this transformation is demonstrated by a broad substrate scope (>50 examples), good functional group tolerance and facile product modification.
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