Crystal structure and luminescence properties of the blue-green-emitting Ba 9 (Lu, Y) 2 Si 6 O 24 :Ce 3 + phosphor.

Samples of the Ba9 (Lu2-x Yx )Si6 O24 :Ce3 + (x = 0-2) blue-green phosphors were synthesized by solid-state reactions. All the samples exhibited a rhombohedral crystal structure. As the Y3 + concentration increased, the diffraction peaks shifted to the small angle region and the lattice parameters increased due to the larger ionic radius of Y3 + (r = 0.900 Å) compared with that of Lu3 + (r = 0.861 Å). Under 400 nm excitation, samples exhibited strong blue-green emissions around 490 nm. The emission bands had a slight blue shift that resulted from weak crystal-field splitting with increasing Y3 + concentration. Luminescence intensity and quantum efficiency (QE) decreased with increasing Y3 + concentration. The internal QE decreased from 74 to 50% and the external QE decreased from 50 to 34% as x increased from 0 to 2. The thermal stability of the Lu series was better than that of the Y-series. The excitation band peak around 400 nm matched well with the emission light from the efficient near-ultraviolet (NUV) chip. These results indicate promising applications for these NUV-based white light-emitting diodes.