Electrochemical Oxidation of [1-X-12-I-CB 11 Me 10 - ] Anions: Formation of Borenium Ylides [12-Dehydro-1-X-CB 11 Me 10 ] and Iodonium Ylide Anions [{12-(1-X-CB 11 Me 10 - )} 2 I + ].

Cyclic voltammograms of 12-iodinated icosahedral carborane anions [1-X-12-I-CB11 Me10 - ] (X = H, CH3 , C2 H5 , C3 H7 , C4 H9 , C6 H13 , and COOCH3 ) show two one-electron anodic oxidation peaks at the Pt electrode in liquid SO2 . Oddly, the first is irreversible and the second partially reversible. Mass spectrometry of the principal anionic product of preparative anodic oxidation of [1-H-12-I-CB11 Me11 - ], identical with the anionic product of its reaction with [Et3 Si-H-SiEt3 ]+ and/or Et3 Si+ , allows it to be identified as the iodonium ylide anion [{12-(1-H-CB11 Me10 - )}2 I+ ]. Its reversible oxidation to a neutral ylide radical [{12-(1-H-CB11 Me10 • )}{12-(1-H-CB11 Me10 - )}I+ ] is responsible for the second peak. A DFT geometry optimization suggests that both the ylide anion and the ylide radical are very crowded and have an unusually large C-I-C valence angle of ∼132°; they are the first compounds with two bulky highly methylated CB11 cages attached to the same atom. Molecular iodine is another product of the electrolysis. We propose an electrode mechanism in which initial one-electron oxidation of [1-X-12-I-CB11 Me10 - ] is followed by a transfer of an iodine atom from the B-I bond to SO2 to yield a weakly bound radical ISO2 • which disproportionates into SO2 and I2 . The other product is the borenium ylide [12-dehydro-1-X-CB11 Me10 ], which has a strongly Lewis acidic naked vertex in position 12 that rapidly adds to another [1-X-12-I-CB11 Me10 - ] anion to form the observed stable ylide anion [{12-(1-X-CB11 Me10 - )}2 I+ ]. In acetonitrile, where it presumably exists as a solvent adduct, [12-dehydro-1-X-CB11 Me10 ] has been trapped with H2 O and, to a small extent, with MeOH, but not with several other potential trapping agents.