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Journal Article
Research Support, Non-U.S. Gov't
Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant.
Chemical Communications : Chem Comm 2016 December 23
The synthesis of a wide variety of carbamates from amines, alcohols and carbon monoxide has been achieved by means of a Rh-catalysed oxidative carbonylation reaction that uses Oxone as a stoichiometric oxidant. In-depth studies on the reaction mechanism shed light on the intimate role of Oxone in the catalytic cycle.
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