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π-Conjugated Lewis Base: Efficient Trap-Passivation and Charge-Extraction for Hybrid Perovskite Solar Cells.

Yuze Lin, Liang Shen, Jun Dai, Yehao Deng, Yang Wu, Yang Bai, Xiaopeng Zheng, Jiayu Wang, Yanjun Fang, Haotong Wei, Wei Ma, Xiao Cheng Zeng, Xiaowei Zhan, Jinsong Huang
Advanced Materials 2017 Februrary
A π-conjugated Lewis base is introduced into perovskite solar cells, namely, indacenodithiophene end-capped with 1.1-dicyanomethylene-3-indanone (IDIC), as a multifunctional interlayer, which combines efficient trap-passivation and electron-extraction. Perovskite solar cells with IDIC layers yield higher photovoltages and photocurrents, and 45% enhanced efficiency compared with control devices without IDIC.

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