Add like
Add dislike
Add to saved papers

Synthesis and crystal structure of tri-carbonyl-chlorido-{1-[(pyridin-2-yl-methyl-idene)amino]-adamantane}rhenium(I).

The title compound, [ReCl(pyAm)(CO)3], where pyAm is 1-[(pyridin-2-yl-methyl-idene)amino]-adamantane (C16H20N2), was synthesized from the reaction of [ReCl(CO)5] and pyAm in an equimolar ratio. The Re(I) atom resides in an octa-hedral C3ClN2 coordination sphere. The Re-C bond trans to the chloride ligand is noticeably longer compared to the other two Re-C distances. Weak C-H⋯Cl hydrogen-bonding inter-actions consoldiate the packing of the mol-ecules. In this design, the pyAm ligand was employed due to its well-known pharmacokinetic properties.

Full text links

We have located links that may give you full text access.
Can't access the paper?
Try logging in through your university/institutional subscription. For a smoother one-click institutional access experience, please use our mobile app.

For the best experience, use the Read mobile app

Mobile app image

Get seemless 1-tap access through your institution/university

For the best experience, use the Read mobile app

All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.

By using this service, you agree to our terms of use and privacy policy.

Your Privacy Choices Toggle icon

You can now claim free CME credits for this literature searchClaim now

Get seemless 1-tap access through your institution/university

For the best experience, use the Read mobile app