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Acute toxicity of organic antifouling biocides to phytoplankton Nitzschia pungens and zooplankton Artemia larvae.

Marine Pollution Bulletin 2017 November 31
The toxicity of the antifouling biocides Irgarol 1051, Diuron, Chlorothalonil, Dichlofluanid, Sea-nine 211, Copper pyrithione, Zinc pyrithione, Ziram and Zineb were evaluated on Nitzschia pungens and Artemia larvae. Results showed that EC50 for Irgarol 1051 was 0.586μgl-1 was the strongest effect on N. pungens following by Copper pyrithione (4.908μgl-1 ), Ziram (5.421μgl-1 ), Zinc pyrithione (5.513μgl-1 ), Diuron (6.640μgl-1 ), Zineb (232.249μgl-1 ), Sea-nine 211(267.368μgl-1 ), Chlorothalonil (360.963μgl-1 ) and Dichlofluanid (377.010μgl-1 ) in 96h. In Artemia larvae, the biocides were evaluated the LC50 for larval survivals at 48h. Sea-nine 211 and Copper pyrithione were 0.318 and 0.319mgl-1 . Chlorothalonil, Zinc pyrithione and Ziram were 2.683, 3.147 and 4.778mgl-1 . Irgarol 1051, Diuron, Zineb and Dichlofluanid were 9.734, 30.573, 41.170 and 154.944mgl-1 . These results provide baseline data concerning the toxicity of antifouling biocides against marine environment.

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