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Rh-Catalyzed Chemo- and Enantioselective Hydrogenation of Allylic Hydrazones.
Chemistry : a European Journal 2017 January 24
A highly efficient P-stereogenic diphosphine-rhodium complex was applied to the chemo- and enantioselective hydrogenation of allylic hydrazones for the synthesis of chiral allylic hydrazines in 89-96 % yields and with 82-99 % ee values. This methodology was successfully applied to the preparation of versatile chiral allylic amine derivatives.
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