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Journal Article
Research Support, Non-U.S. Gov't
Stable, crystalline boron complexes with mono-, di- and trianionic formazanate ligands.
Chemical Communications : Chem Comm 2017 January 4
Redox-active formazanate ligands are emerging as tunable electron-reservoirs in coordination chemistry. Here we show that boron diphenyl complexes with formazanate ligands, despite their (formal) negative charge, can be further reduced by up to two electrons. A combined crystallographic, spectroscopic and computational study establishes that formazanate ligands are stable in mono-, di- and trianionic form.
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