We have located links that may give you full text access.
Metal-Organic Frameworks Constructed from a New Thiophene-Functionalized Dicarboxylate: Luminescence Sensing and Pesticide Removal.
ACS Applied Materials & Interfaces 2017 May 4
A family of thiophene-based metal-organic frameworks (MOFs), [Zn(L)(BBI)·(H2 O)2 ] (1) (BBI = 1,1'-(1,4-butanediyl)bis(imidazole)) and [Cd(L)(TPOM)0.75 ]·xS (2) (TPOM = tetrakis(4-pyridyloxy-methylene) methane, S represents noncoordinated solvent molecules) was constructed by employing a new linear thiophene-functionalized dicarboxylic acid (benzo-(1,2;4,5)-bis(thiophene-2'-carboxylic acid, H2 L) to assemble with d10 ions in the presence of a flexible ancillary ligand under solvothermal conditions, which exhibit diverse structures. Most strikingly, both compounds 1 and 2 could be efficient luminescent sensory materials that are highly selective and sensitive to environmental contaminants, especially for Hg(II), Cu(II), Cr(VI), and salicylaldehyde, and yet remain unaffected by other molecules that may coexit. Furthermore, this is the first report on MOF-based sensors capable of recyclable detection of Hg(II), Cr(VI), and salicylaldehyde so far. The luminescent sensing mechanism was studied in detail as well. In addition, compound 2 is one of the rare examples of high-performance MOFs trapping 2,4-dichlorophenol from the wasted methanol solution.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app