Carbonized Electrospun Nanofiber Sheets for Thermophones.

Thermoacoustic performance of thin freestanding sheets of carbonized poly(acrylonitrile) and polybenzimidazole nanofibers are studied as promising candidates for thermophones. We analyze thermodynamic properties of sheets using transport parameters of single nanofibers and their aligned and randomly electrospun thin film assemblies. The electrical and thermal conductivities, thermal diffusivity, heat capacity, and infrared blackbody radiation are investigated to extract the heat exchange coefficient and enhance the energy conversion efficiency. Spectral and power dependencies of sound pressure in air are compared with carbon nanotube sheets and theoretical prediction. Despite lower thermoacoustic performance compared to that of CNT sheets, the mechanical strength and cost-effective production technology of thermophones make them very attractive for large-size sound projectors. The advantages of carbonized electrospun polymer nanofiber sheets are in the low frequency domain (<1000 Hz), where the large thermal diffusion length diminishes the thermal inertia of thick (∼200 nm) nonbundled fibers and the high intrinsic thermal conductivity of fibers enhances the heat exchange coefficient. Applications of thermoacoustic projectors for loudspeakers, high power SONAR arrays, and sound cancellation are discussed.