JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
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Reaction of C 60 with Inactive Secondary Amines and Aldehydes and the Cu(OAc) 2 -Promoted Regioselective Intramolecular C-H Functionalization of the Generated Fulleropyrrolidines.

The thermal reaction of C60 with aromatic aldehydes and inactive secondary amines for the stereoselective synthesis of trans-1,2,5-trisubstituted fulleropyrrolidines has been developed. Moreover, when an o-hydroxyl group was located at the phenyl ring of the generated fulleropyrrolidines, the Cu(OAc)2 -promoted regioselective intramolecular C-O coupling reaction occurred to generate unique tricycle-fused fullerene derivatives.

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