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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
Palladium-Catalyzed Decarboxylative Synthesis of Arylamines.
Organic Letters 2016 November 5
A novel approach has been developed for the synthesis of arylamines via the palladium-catalyzed intramolecular decarboxylative coupling (IDC) of aroyloxycarbamates, obtained in situ by reacting aryl carboxylic acids with hydroxycarbamates. The reaction offers facile access to structurally diverse arylamines with the site-specific formation of the C(sp2 )-N bond under mild conditions.
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